Lithium manganese oxide cathodes with high capacity and stabilit

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

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429217, H01M 450

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active

057631204

ABSTRACT:
A method for reducing capacity fading of an LiMn.sub.2 O.sub.4 spinel electrode active material comprising substituting a minor amount of Z for Mn in the LiMn.sub.2 O.sub.4 active material, where Z is a metal element having a +4 (IV) valence state and is characterized by an ability to form tetravalent chlorides. The Z substituted LiMn.sub.2 O.sub.4 active material is further characterized by a lesser rate of capacity loss with cycling as compared to LiMn.sub.2 O.sub.4 active material.

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