Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal
Patent
1977-04-13
1980-02-05
Schafer, Richard E.
Chemistry of inorganic compounds
Treating mixture to obtain metal containing compound
Radioactive metal
423 11, 423162, 423194, 423252, 423253, 423356, 423357, 423397, C01F 1500, C01G 5600
Patent
active
041872800
ABSTRACT:
Radiation-contaminated ammonium nitrate is heated in solution to about 100.degree. C. in the presence of finely powdered calcium oxide or lithium hydroxide. Ammonia and water vapor are given off leaving an alkaline or alkaline earth nitrate which can then be safely decomposed by calcination into a metal oxide and oxides of nitrogen. The metal oxide can be recycled in a continuation of the process. The oxides of nitrogen can be passed through water to produce nitric acid useable in dissolving oxides of fissionable materials and the ammonia may be used in aqueous solution to react with nitrates of nuclear fuel or breeder metals in the very process that produces the by-product ammonium nitrate. Thus, all by-products and reagents can be reconverted and recycled.
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Comprehensive Inorganic Chemistry, vol. 1, Pergamon Press, 1973, pp. 360, 2-473, 653.
Sienko, M. J. et al., Chemistry, 3rd Ed. 1966, McGraw-Hill, N.Y. pp. 519, 517.
Morschl Paul
Zimmer Erich
Kernforschungsanlage Julich Gesellschaft mit beschrankter Haftun
Schafer Richard E.
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