Conversion of alpha-methylstyrene-type monomers in the formation

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525272, 525314, 526174, 526181, C08F 448

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043025595

ABSTRACT:
Copolymers of alpha-methylstyrene-type monomers and conjugated diene monomers are prepared by polymerizing an alpha-methylstyrene monomer using a first polar activator, adding a small amount of a conjugated diene monomer to cap the block of alpha-methylstyrene-type monomer polymer, and further adding a conjugated diene monomer and polymerizing with a second polar activator effective for copolymerization of residual alpha-methylstyrene-type monomer. The resulting copolymer can be coupled to form linear or radial block copolymers.

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Whitby-Synthetic Rubber, pp. 746-747 (Wiley), 1954.
Karoly, "An Alpha-Methylstyrene Isoprene Block Copolymer", Div. Poly Chem., Poly. Reprints, vol. 10, #2, pp. 837-842.

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