Polysaccharide modification in densified fluid

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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536 58, 536 84, 536 69, 536111, 5361231, 53612312, 536124, C08B 3104, C08B 3110, C08B 3700

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active

059773480

ABSTRACT:
This invention relates to a process for chemically modifying polysaccharides in a densified fluid. In particular, the modification includes esterification and/or etherification of a starch in supercritical carbon dioxide. The process is advantageous in that it allows for a high degree of substitution without the use of organic solvents or repeated reactions.

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A. R. Berens, Gary S. Huvard, Richard W. Korsmeyer, F. W. Kunig, Application of Compressed Carbon Dioxide in the Incorporation of Additives into Polymers, The BF Goodrich Company, Research & Development Center, Brecksville, Ohio, pp. 231-242, 1988.
Manssur Yalpani, "Supercritical fluids: puissant media for the modification of polymers and biopolymers", Polymer 1993 vol. 34, No. 5, pp. 1102-1105, 1992.
Manssur Yalpani, "New Approaches to the Synthesis of Glycan Derivatives", Carbohydrates and Carbohydrate Polymers, Analysis, Biotechnology, Modification, Antiviral, Biomedical and Other Applications, Yalpani, M. (ed.), .COPYRGT.ATL Press, 1993.
Hyun-Song Lee, Woo Gi Lee, Sang-Woo Park, Huen Lee and Ho Nam Chang, "Starch Hydrolysis Using Enzyme in Supercritical Carbon Dioxide", Biotechnology Techniques, vol. 7 No. 4 (Apr. 1993) pp. 267-270.

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