Preparation of alkyl primary amines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C09C 8520

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049279696

ABSTRACT:
Alkyl primary amines, e.g., tertiary alkyl primary amines, are prepared by reaction of the corresponding alkyl primary isocyanates with an alkanolamine to form an intermediate area reaction product, followed by heating to decompose the urea reaction product and form the amine product. The amine product can be recovered in high yield by vacuum distillation.

REFERENCES:
patent: 4111917 (1978-09-01), Larsen
patent: 4547265 (1985-10-01), Forgione et al.
Wicks et al., Jol. of Coating Tech., "Reaction of N-(2-Hydroxyethyl)Amide Compounds", Jul. 1985, pp. 51-61.
Merck Index, 8th ed., 1968, pp. 1094, "Urea".
Morrison and Boyd, Organic Chemistry, 3rd ed., 1974, p. 686 "Urea".

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