Electrochemical synthesis of ternary phosphides

Details Electrochemical synthesis of ternary phosphides Electrochemical synthesis of ternary phosphides

1986-03-28

1987-01-20

Williams, Howard S.

Chemistry: electrical and wave energy

Processes and products

C25B 100

Patent

active

046378642

ABSTRACT:
This invention comprises a method of synthesizing ternary phosphide compos of the general formula M(II)M(IV)P.sub.2 by fused salt electrolysis in which a melt powder mixture containing phosphorus compounds is introduced into an electrolytic apparatus containing a liquid group II metal cathode and a group IV metal or semiconductor source. Electrolysis occurs under controlled conditions in which oxygen is excluded as an impurity to produce the desired ternary phosphide compounds.

REFERENCES:
patent: 3725221 (1973-04-01), Gomes et al.

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