Phosphoryl sulfenyl chloride olefin adducts

Details Phosphoryl sulfenyl chloride olefin adducts Phosphoryl sulfenyl chloride olefin adducts

1977-01-13

1978-09-05

Sutto, Anton H.

Chemistry of carbon compounds

Dipeptides, e.g., aspartame, anserine, carnosine, etc.

260957, 260963, C07F 9165

Patent

active

041120248

ABSTRACT:
Phosphorylsulfenyl halides are added to monoolefins, multiolefins, conjugated multiolefins and acetylenic compounds. 1,2-Markownikov oriented adducts are the principle products when conjugated diolefins are employed as the starting feedstock. Anti-Markownikov adducts are obtained as major products when unsymmetrical monoolefins and nonconjugated multiolefins are used as the starting material. The addition reactions are conducted at low temperatures. The materials which are obtained are of interest as pesticides and as intermediates in the synthesis of pesticides.

REFERENCES:
patent: 3081329 (1963-03-01), Vegter
Muller et al., "J. Org. Chem." vol. 31, pp. 3537-3543 (1966).
Michalski et al., 37 Chem. Abst." vol. 51, p. 2535, 1957.

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