Catalytically active porous nickel electrodes

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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204290R, 204292, C25B 1103, C25B 1106

Patent

active

041168046

ABSTRACT:
An improved electrode having a porous nickel surface layer of greater than 75 microns in thickness and at least 11% in porosity is produced by a process which includes interdiffusing aluminum and nickel at a temperature of at least 660.degree. C. to form a nickel-aluminum alloy layer from which aluminum is subsequently selectively dissolved. When used as a cathode in an electrolytic cell for producing hydrogen, chlorine and caustic from brine, the improved electrode exhibits exceptionally low hydrogen overvoltage.

REFERENCES:
patent: 1263959 (1918-04-01), Swartley, Jr.
patent: 1427171 (1922-08-01), Smith
patent: 2969315 (1961-01-01), Bacon
patent: 3441495 (1969-04-01), Colman
patent: 3900602 (1975-08-01), Rummel
patent: 3945907 (1976-03-01), Gokhale

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