Process for selective formation of C.sub.4 compounds and thiol-c

Details Process for selective formation of C.sub.4 compounds and thiol-c Process for selective formation of C.sub.4 compounds and thiol-c

1980-12-11

1982-07-13

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568888, 568902, C07C 2722, C07C 4550

Patent

active

043396100

ABSTRACT:
C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and a thiol defined by the formula:

REFERENCES:
patent: 2623906 (1952-12-01), Gresham
patent: 3248432 (1966-04-01), Riley et al.
patent: 3285948 (1966-11-01), Butter
patent: 3387043 (1968-06-01), Kuraishi et al.
patent: 4133966 (1979-01-01), Pretzer et al.
patent: 4168391 (1979-09-01), Slinkard et al.
patent: 4171461 (1979-10-01), Bartish
patent: 4262154 (1981-04-01), Gane et al.

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