Substitution of Sn in place of Al in the framework of molecular

Chemistry of inorganic compounds – Zeolite – Isomorphic metal substitution

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423715, 423DIG15, 423DIG25, 423DIG26, 423DIG28, 502 77, 502 78, 502 79, 502 85, C01B 3906, C01B 3920, C01B 3926, C01B 3932

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055187080

ABSTRACT:
Molecular sieve compositions are prepared by extracting aluminum and substituting chromium and/or tin for extracted aluminum to give molecular sieve products containing framework chromium and/or tin atoms. The process of preparing the chromium and/or tin-containing molecular sieves involves contacting a starting molecular sieve with a solution or slurry of at least one of a fluoro salt of chromium or a fluoro salt of tin under effective process conditions to provide for aluminum extraction and substitution of chromium and/or tin.

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Atlas of Zeolite Structures, Meier et al. 1992 pp. 128-129.

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