1,3,2-dioxastannolane-modified elastomers and compositions conta

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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5253328, 5253329, 5253331, 5253332, 525370, C08F 842

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active

052449661

ABSTRACT:
Modification of lithium-terminated elastomer intermediates by reaction under anionic conditions with 1,3,2-dioxastannolanes provides tin-containing elastomers with improved hysteresis properties. In specific examples, modification of a lithium-terminated styrene-butadiene rubber with a dioxastannolane derived from reaction of dibutyl tin(IV)oxide with an alkyl-substituted 1,3-pentane provides tin-modified SBRs with lowered tan delta properties. Such modified elastomers are useful in making tread portions of pneumatic tires.

REFERENCES:
patent: 3426006 (1969-02-01), Nutzel et al.
patent: 3439049 (1969-04-01), Trepka
patent: 4414372 (1983-11-01), Farnham et al.
patent: 4429091 (1984-01-01), Hall
patent: 4614771 (1986-09-01), Watanabe et al.
patent: 4616069 (1986-10-01), Watanabe et al.
patent: 4736003 (1988-04-01), Schneider et al.
"the Organic Chemistry of Tin", Interscience Publishers, 1971, by Wilhelm P. Neumann.
"Preparation of Some Trialkyltin-lithium Compounds", J. Am. Chem. Soc., 75, 2507-2508 (1953) by Gillman and Rosenberg.
"Preparation and Reactions of Trialkyltin-lithium", J. Org. Chem, 28, 237-239 (1963), by Tamborski, Ford and Soloski.
"Some Reactions of Tributyl-and Triphenyl-stannyl Derivatives of Alkali Metals", J. Chem. Soc., 1961, 618-622 by Blake, Coates and Tate.
"New Perfectly Difunctional Organolithium Initiators for Block Copolymers Synthesis: Synthesis of dilithium initiators in the absence of polar additives" Polymer, vol. 22, Dec. 1981, p. 1724, by Guyot, et al.
"A Bifunctional Anionic Initiator Soluble in Nonp14 Polar Solvents", Makromol. Chem. 179, 1978, pp. 551-555, by Beinert, et al.
"Bifunctional Anionic Initiators: A Critical Study and Overview", Makromol. Chem. 1986, 1985, pp. 2017-2024, by Bandermann, et al.
"Anionic Polymerization Initiators Containing Protected Functional Groups and Functionally Terminated Diene Polymers", Journal of Polymer Science, Polymer Chemistry Edition, vol. 12, pp. 153-166, by Schulz (1974).
"Specific Functionalization of Polymers by Carboxyl Groups", Makromol. Chem. 179, 1978, pp. 1383-1386, by Broze, et al.
"3-Dimethylaminopropyl-Lithium--An analytical and Kinetic Investigation of a New Initiator System for Polymer Synthesis", European Polymer Journal, vol. 11, 1975, pp. 699-704, by Eisenbach, et al.
"Organotin-Mediated Monoacylation of Diols with Reserved Chemoselectivity: A Convenient Synthetic Method", J. Org. Chem., 55, 5132-5139 (1990) by G. Reginato, et al.

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