Preparation of an active olefin polymerization catalyst

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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252429A, 252442, B01J 3102, B01J 2706

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active

040779033

ABSTRACT:
A titanium catalyst for polymerization of olefins is prepared by reduction of TiCl.sub.4 with a mixture of AlEt.sub.2 Cl and AlEt.sub.3, where at high AlEt.sub.3 to AlEt.sub.2 Cl ratios the aluminum reducing agents are added to the TiCl.sub.4 solution. The reduction is performed from -50.degree. to 0.degree. C in a hydrocarbon and the reduced titanium compound is activated by heating to a higher temperature and subsequently is used with a cocatalyst for polymerization of olefins.

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patent: 3226336 (1965-12-01), Schrage et al.
patent: 3825524 (1974-07-01), Wada et al.
patent: 3905915 (1975-09-01), Wristers

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