Preparation of phenol by direct hydroxylation of benzene

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3900

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050012800

ABSTRACT:
Phenol is prepared by directly hydroxylating benzene with nitrous oxide, preferably in vapor phase, on a substrate of acidified zeolite particulates, advantageously ZSM-5 zeolite particulates, and such acidified zeolite particulates having a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 of greater than about 90, preferably up to 500.

REFERENCES:
patent: 4578521 (1986-03-01), Chang et al.
Suzuki et al. Chemical Soc. of Japan Chemistry Letters, pp. 953-956 1988.

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