Polymerization of fluoromonomers in carbon dioxide

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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5262191, 526247, 526250, 526254, 526255, 526942, C08F 200, C08F 402, C08F 1418

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06103844&

ABSTRACT:
Polymerization of vinylidene fluoride in carbon dioxide media is effectively initiated by dialkyl(2,2-azobisisobutyrate). Methyl is a preferred alkyl.

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Kirk-Othmer--Encyclopedia of Chemical Technology, 4.sup.th Edition, vol. 11, p. 694 (1994).
Sheppard & Kamath, The Selection and Use of Free Radical Initiators, Polymer Engineering and Science 19, 597 (1979).

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