Catalyst productivity in the polymerization of olefins

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526124, 526901, 526351, C08F 234, C08F 1000

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active

049819291

ABSTRACT:
Highly stereospecific olefin polymers are obtained in enhanced yield in a continuous gas-phase fluid bed process for polymerizing alpha monoolefins employing a catalyst system comprising (a) a solid titanium-containing procatalyst, (b) an organoaluminum activator compound, and (c) a selectivity control agent, by continuously adding dialkylaluminum halide to the reactor during polymerization and conducting polymerization at a temperature of 0.1.degree. to 5.0.degree. C. above the dew point temperature of the cycle gas in the reactor.

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