Nitrogen-containing perfluoroalkanoyl peroxide and method for pr

Details Nitrogen-containing perfluoroalkanoyl peroxide and method for pr Nitrogen-containing perfluoroalkanoyl peroxide and method for pr

1992-09-08

1993-05-04

Cintins, Marianne M.

Organic compounds -- part of the class 532-570 series

Organic compounds

Chalcogen in the nitrogen containing substituent

544 66, 540596, C07D26530

Patent

active

052083390

ABSTRACT:
A nitrogen-containing perfluoroalkanoyl peroxide is provided which is represented by the formula: ##STR1## wherein Rf.sub.1 and Rf.sub.2 independently stand for an alkyl group of 1 to 5 carbon atoms, provided that Rf.sub.1 and Rf.sub.2 are joined to each other in one of the three patterns of union, 1) direct union, 2) union through the medium of an oxygen atom or 3) union through the medium of a nitrogen atom to form one of the three rings, i.e. five-membered ring, six-membered ring or seven-membered ring. The nitrogen-containing perfluoroalkanoyl peroxide is produced by a method which comprises oxidizing a compound represented by the following formula: ##STR2##

REFERENCES:
Journal of Flourine Chemistry, vol. 22, 1983, pp. 541-556, Fuchikami, et al., "Direct Perfluoroalkylation of Functionalized Benzenes with Perfluoroalkyl Halides and Copper Bronze".
Journal of Organic Chemistry, vol. 47, 1982, pp. 2009-2013, Z. Chengxue, et al., "Thermal Decomposition of Some Perfluoro-and Polyfluorodiacyl Peroxides".

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