Preparation of 1,1,1,2,3-pentafluoropropane by reduction of 1,2,

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570151, C07C 1724, C07C 1902

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053150481

ABSTRACT:
The present invention relates to a process for the reductive dechlorination of ClCF.sub.2 CFClCF.sub.2 Cl to CF.sub.3 CHFCH.sub.2 F comprising the step of contacting 1,2,3-trichloropentafluoropropane and H.sub.2 in the presence of a catalyst selected from the group consisting of palladium, platinum, ruthenium, rhodium, iridium and mixtures thereof supported on alumina under reaction conditions sufficient to produce a product stream containing 1,1,1,2,3-pentafluoropropane.

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Barlow, M. G. et al., "Heterocyclic Polyfluoro-compounds. Part 31. Photo chemical . . . ", J. Chem. Soc. Perkin Trans. I, (1980), pp. 2258-2267.
Henne, A. L. et al., "Perfluorinated Olefins", J. Am. Chem. Soc., (1948), 70, pp. 130-132.
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