Silicon-bridged transition metal compounds

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526127, 526160, 526170, 5263482, 5263484, 502152, C08F 442, C08F 464

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active

053149734

ABSTRACT:
Silicon-bridged transition metal compounds and their use as .alpha.-olefin polymerization catalysts are disclosed. A chiral silicon-bridged metallocene catalyst polymerizes .alpha.-olefins to high isotacity with a minimum of inversions at high rates of catalyst activity. The catalyst is easily made in high yields and readily separated from atactic meso forms.

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Transition Metals and Organometallics as Catalysts for Olefin Polymerization-W. Kaminsky and H. Sion (Eds.), Proceedings of an International Symposium, Hamburg, (FRG), Sep. 21-24, 1987.
Crystal Structures and Stereospecific Polypropylene Polymerizations with Chiral Hafnium Metallocene Catalysts J. Am. Chem. Soc. 109, 6544 (1987) of Ewen et al.
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