Process to incorporate nitrogen at an interface of a dielectric

Fishing – trapping – and vermin destroying

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437241, 437242, H01L 21225

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054647924

ABSTRACT:
Nitrogen is piled-up at a top interface of a gate dielectric layer by a process of the present invention. A gate dielectric layer (14) is formed on a substrate (12). A buffer layer (16), such as polysilicon, is formed on the dielectric layer. A nitrogen source layer (18), such as oxynitride, is formed on the buffer layer. The device is annealed to drive nitrogen from the source layer through the buffer layer and to an interface (15) between the polysilicon and the dielectric, resulting in a high nitrogen concentration at this interface. A nitrogen concentration may also be achieved at an interface (13) between the dielectric layer and the substrate.

REFERENCES:
patent: 5063423 (1991-11-01), Fuji et al.
Yoshio Okada et al., "Relationship between growth conditions, nitrogen profile, and charge to breakdown of gate oxynitrides grown from pure N20", American Institute of Physics/1993, Applied Physics Letter 63, 12 Jul. 1993, pp. 194-196.
G. W. Yoon et al., "MOS Characteristics of NH3-Nitrided N20-Grown Oxides", IEEE Electron Device Letters, (14), No. 4, Apr. 1993, pp. 179-181.
S. Ohnishi et al., "Ultrathin Oxide/Nitride/Oxide/Nitride Multilayer Films for Mbit DRAM Capacitors", Solid State Devices & Materials, Ext. Abstracts of '92 Int. Conf. Aug., pp. 67-69.
S. Haddad et al., "Improvements of Thin-Gate Oxide Integrity Using Through-Silicon-Gate Nitrogen Ion Implantation", IEEE Electron Device Letters, vol. EDL-8 No. 2, Feb. 1987, pp. 58-60.
J. Ahn et al., "Furnace Nitridation of Thermal SiO2 in Pure N2O Ambient for ULSI MOS Applications", IEEE Electron Device Letters, vol. 13, No. 2, Feb. 1992, pp. 117-119.
G. Q. Lo et al., "Improved Hot-Carrier Immunity in CMOS Analog Device With N2O-Nitrided Gate Oxides" IEEE Electron Device Letters, vol. 13, No. 9, Sep. 1992, pp. 457-459.
H. Fukuda et al., "High-Performance Scaled Flash-Type EEPROMs With Heavily Oxynitrided Tunnel Oxide Films", IEEE IEDM 1992, pp. 465-468.
P. Molle et al., "Sealed Interface Local Oxidation by Rapid Thermal Nitridation" J. Electrochem. Soc., vol. 138, No. 12, Dec. 1991, The Electrochemical Society, pp. 3732-3738.
G. Q. Lo et al., "Improved Performance and Reliability of MOSFETs With Ultrathin Gate Oxides . . . " VLSI Symposium 1991, pp. 43-44.
Research Disclosure Document #18756, "Under-grown multiple dielectric-layer semiconductor device", Derwent Publications, Nov. 1979, pp. 652-653.

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