Polyimide precursor composition, method of forming polyimide fil

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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428395, 4284111, 4284735, 430170, 430191, 430192, 4302701, 528170, 528172, 528173, 528176, 528183, 528185, 528188, 528220, 528229, 528310, 528322, 528342, C08G 7310

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057566500

ABSTRACT:
A polyimide precursor composition, which comprises, a polyamic acid having a repeating unit represented by the following general formula (PA), and at least one kinds of cure accelerator selected from the group consisting of a substituted or unsubstituted nitrogen-containing heterocyclic compound exhibiting an acid dissociation index "pKa" of a proton complex ranging from 0 to 8 in an aqueous solution thereof, or an N-oxide compound of said nitrogen-containing heterocyclic compound (AC1), a substituted or unsubstituted amino acid compound (AC2), and an aromatic hydrocarbon compound or an aromatic heterocyclic compound having a molecular weight of 1,000 or less and two or more hydroxyl groups (AC3): ##STR1## wherein .phi. is a quadrivalent organic group, .phi. is a bivalent organic group, R is a substituted or unsubstituted hydrocarbon group, organosilicic group or hydrogen atom.

REFERENCES:
patent: 5578697 (1996-11-01), Kawamonzen et al.
patent: 5585217 (1996-12-01), Oba
Masayuki Oba, "Effect of Curing Accelerators on Thermal Imidization of Polyamic Acids at Low Temperature", Journal of Polymer Science: Part A: Polymer Chemistry, vol. 34, 1996, pp. 651-658.
M. Oba, "Effect of Cure Accelerator on Imidization of Polyamic Acid at Low Temperature", Polymer Preprints, Japan, vol. 43, No. 7, 1994, pp. 2087-2088.
Masayuki Oba, et al., "Synthesis and Evaluation of Positive-Acting Photosensitive Polyimides with Phenol Moiety", Journal of Applied Polymer Science, vol. 58, 1995, pp. 1535-1542.
M. Oba, "Synthesis and Characterization of Positive Working Photosensitive Polyimide", Polymer Preprints, Japan, vol. 42, No. 7, 1993, pp. 2691-2693.

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