Process for the simultaneous manufacture of epsilon-caprolactone

Details Process for the simultaneous manufacture of epsilon-caprolactone Process for the simultaneous manufacture of epsilon-caprolactone

1975-10-08

1977-03-22

Gotts, Lewis

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260530R, 252428, 252429R, 252431C, 252431N, C07D31302

Patent

active

040136914

ABSTRACT:
A cyclohexanone is oxidized by molecular oxygen in the presence of an aldehyde, a soluble compound of a metal selected from the group consisting of iron, palladium, vanadium, chromium, molybdenum, tungsten and cerium, and a compound which has a heterocyclic ring containing at least one nitrogen atom and which acts as a multidantate ligand, to form an epsilon-caprolactone and a carboxylic acid corresponding to the aldehyde.

REFERENCES:
patent: 3025306 (1962-03-01), Guest et al.
patent: 3483222 (1969-12-01), Sennewald
patent: 3541113 (1970-11-01), Hoff

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