Polymer-bound cyclopentadiene metal carbonyl compounds and their

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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20415914, 252428, 252431R, 252431P, 252431N, 260429R, 260429CY, 260429L, 2604297, 2604385R, 260439CY, 521 31, 521 53, 525370, 585645, 585646, B01J 3120, B01J 3124, C07F 1500, C08F 842

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active

043614973

ABSTRACT:
Polymeric catalysts containing groups of the general formula: [--(C.sub.5 R.sub.4)Me(CO).sub.x L.sub.y ].sub.z, wherein (C.sub.5 R.sub.4) is a sustituted or unsubstituted cyclopentadiene group; Me is a transition metal; and L is alkyl or aryl phosphine, alkyl phosphite, nitrosyl, allyl, SnCl.sub.3, halogen or hydrogen. Such groups are bound to polymeric carriers such as polystyrene-based copolymers, silica gel or silicate glass. Processes for preparing such catalysts and methods for their use are also disclosed.

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patent: 4173575 (1979-11-01), Carlock
J. Am. Chem. Soc.-vol. 97:8:Apr. 16, 1975, pp. 2128-2132, "Polystyrene Attached Titanocene Species Preparation & Reactions"-W. D. Bonds, Jr. et al.

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