Process for the preparation of an olefin polymer using metalloce

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

525268, 526121, 526122, 526134, 526160, 526351, C08F 4602, C08F 1000

Patent

active

058695842

ABSTRACT:
A highly effective catalyst system for the polymerization of olefins comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## in which, preferably M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.5 is hydrogen or alkyl, R.sup.3 and R.sup.4 are alkyl, where R.sup.3, R.sup.4 and R.sup.5 may be halogenated, --(CR.sup.7 R.sup.8).sub.m --R.sup.6 --(CR.sup.7 R.sup.8).sub.n -- is a single- or multi-membered chain in which R.sup.6 may also be a (substituted) heteroatom, and m+n is zero or 1.

REFERENCES:
patent: 4769510 (1988-09-01), Kaminsky et al.
patent: 4794096 (1988-12-01), Ewen
patent: 4892851 (1990-01-01), Ewen et al.
patent: 4931417 (1990-06-01), Miya et al.
patent: 5004820 (1991-04-01), Buchwald et al.
patent: 5087677 (1992-02-01), Brekner et al.
patent: 5103030 (1992-04-01), Rohrmann et al.
patent: 5120867 (1992-06-01), Welborn, Jr.
patent: 5145819 (1992-09-01), Winter et al.
patent: 5243001 (1993-09-01), Winter et al.
patent: 5276208 (1994-01-01), Winter et al.
patent: 5296434 (1994-03-01), Karl et al.
patent: 5324800 (1994-06-01), Welborn, Jr.
patent: 5329031 (1994-07-01), Miyake et al.
patent: 5329033 (1994-07-01), Spaleck et al.
patent: 5374752 (1994-12-01), Winter et al.
Spaleck et al., New J. Chem., "Stereorigid Metallocenes: Correlations Between Structure and Behaviour in Homopolymerizations of Propylene", vol. 14, pp. 499-403 (1990).
Roll, V.W., et al., Angew. Chem., "Stereo- und Regioselektivatat von chiralen, alkylsubstituierten ansa-Zirconocen-Katalysatoren bei der Methylalumoxan-aktivierten Propen-Polymerization", vol. 102, No. 3, pp. 339-341 (1990).
Piccoliovazzi, N. et al., Organometallics, "Electronic Effects in Homogeneous Indenylzirconium Ziegler-Natta Catalysts", vol. 9, pp. 3098-3105 (1990).
Miyamota, T.K., et al., Chemistry Letters, The Chemical Society of Japan, "a Bulky Ligand and its Organometallic Compound: Synthesis of Heptamethylidene and a Ferrocene-Type Complex, Fe(n.sup.5 -C.sub.9 Me.sub.7).sub.2 ", pp. 729-730 (1981).
Esperas, S., Acta Chemica Scandinavica, "The Crystal and Molecular Structure of Cyano(methylisocyanide)gold(I)", A 30, No. 7, pp. 527-530 (1976).
Adcock et al., Austr. J. Chem., vol. 29, "Substituent Effects by .sup.19 F Nuclear Magnetic Resonance: Polar and .pi.-Electron Effects", pp. 2571-2581.
Marechal et al., Bull. Soc. Chim. Fr. 6, "Homopolymerisation cationlique des dimethyl-4,7,dimethyl-4,6 et dimethyl-5,6 indenes", No. 348, pp. 1981-2039, (1969).
Chemical Abstracts 90:567 103691p; (1978).
Criegee et al., Chem. Ber., vol. 94, "Uber den Nickelkomplex C.sub.18 H.sub.22 Ni und den daraus gewonnenen Kohlenwasserstoff C.sub.13 H.sub.18 ", pp. 3461-3468 (1964).
Hart et al., Notes, J. Am. Chem. Soc., vol. 72, "Acylation-Alkylation Studies", pp. 3286-3287 (1950).
Katz, Thomas J., J. Am. Chem. Soc., "Asymmetric Synthesis of Helical Metallocenes", vol. 108, 1986, pp. 179-181.
Ewen, J.A., et al, J. Am. Chem. Soc., Crystal Structures and Sterospecific Propylene Polymerizations with Chiral Hafnium Metallocene Catalysts, vol. 109, 1987, pp. 6544-6545.
Bulletin de la Societe Chimique de France, "Etude de monomeres halogenes et de leur polymerisation cationique", No. 11, pp. 3092-3095, (1973).
J. Org. Chem., "Friedel-Crafts Reactions of Ethyl Cyclopropanecarboxylate", vol. 46, pp. 3758-3760 (1981).
Soga, K. et al., Macromolecules, "Perfect Conversion of Aspecific Sites into Isopecific Sites in Ziegler-Natta Catalysts", vol. 22, pp. 3824-3826 (1989).
J. Org. Chem., "Friedel-Crafts Chemistry. A Mechanistic Study of the Reaction of 3-Chloro-4'-fluoro-2-methylpropiophenone with AlCl.sub.3 and AlCl.sub.3 -CH.sub.3 NO.sub.2 ", vol. 43, No. 16, pp. 3126-3131 (1978).
Chemical Abstracts, vol. 117, 1992, Lee et al., Electronic Effects of Ziegler-Natta Polymerization of Propylene and Ethylene Using Soluble Metallocene Catalysts.
Journal of the American Chemical Society, Bd. 115, Jul. 14, 1993, J.R. Hart, Predicted Structure Selectivity Trends: Propylene Polymerization with Substituted RAC-(1,2-Ethylenebis(.ETA.5-Indenyl)Zirconium (IV) Catalysts.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for the preparation of an olefin polymer using metalloce does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for the preparation of an olefin polymer using metalloce, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the preparation of an olefin polymer using metalloce will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1949219

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.