Electrogenerative cell for the oxidation or halogenation of hydr

Chemistry: electrical and wave energy – Processes and products

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204 81, 429 17, 429 34, C25B 306

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047311681

ABSTRACT:
An electrogenerative cell and a process for the oxidation or halogenation of hydrocarbons is disclosed wherein a cell body containing a permselective membrane which divides said cell body into anolyte and catholyte compartments containing a liquid electrolyte consisting repectively of anolyte and catholyte and a porous anode and a porous cathode. Anolyte and catholyte compartments are fed respectively with a mixture of a liquid electrolyte and an unsaturated hydrocarbon and a mixture of a liquid electrolyte and a halogen or oxygen, wherein said electrolytes are fed to said cell at ambient or elevated temperature and pressure. A halogenated or oxygenated hydrocarbon is recovered and electrolytes, unsaturated hydrocarbon, halogen or oxygen are recycled to the cell.

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Journal of the Electrochemical Society, vol. 129, No. 9, 1993 (1982)--Kinoshita et al.

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