Polymerization of CO/non-conjugated diene/diol

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymer of an ethylenically unsaturated reactant with a...

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528271, C08G 6702

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active

050496506

ABSTRACT:
Polyesters or polyanhydrides are produced by reaction of non-conjugated dienes with diols or dicarboxylic acids, respectively, in the presence of a catalyst composition formed from a palladium compound, a monodentate phosphorus ligand optionally employed with a bidentate phosphorus ligand and a limited amount of a protonic acid having a pKa below 2, in the substantial absence of water. The polymer products are useful as constituents of sealants, adhesives and paints.

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patent: 4297481 (1981-10-01), Jachimowicz
patent: 4629807 (1986-12-01), Knifton
patent: 4831113 (1989-05-01), Van Broekhoven et al.
patent: 4921937 (1990-05-01), Drent
patent: 4940775 (1990-07-01), Drent

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