Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component
Patent
1987-05-07
1988-12-20
Heller, Gregory A.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Nitrogen or nitrogenous component
B01J 800, C01B 2100
Patent
active
047924390
ABSTRACT:
A process for decreasing the content of nitrogen oxides in flue gases. The process comprising contacting the flue gases with a catalyst. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a layer structure (layer silicate) comprising acid-activated kaolin. The crystalline layer structure of the acid-activated kaolin is essentially retained, while being not yet X-ray amorphous. The acid activation increases the BET surface area at least 15% and preferably at least 50% in terms of the BET surface area of the kaolin before acid activation. The atomic ratio of the silicon in the acid-activated kaolin to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.
REFERENCES:
patent: 3962135 (1976-06-01), Alafandi
patent: 4140654 (1979-02-01), Yoshioka et al.
patent: 4176091 (1979-11-01), Inaba et al.
patent: 4282115 (1981-08-01), Atsukawa et al.
Kochloefl Karl
Maletz Gerd
Schneider Michael
Wernicke Hans J.
Heller Gregory A.
Sud-Chemie Aktiengesellschaft
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