Reactive derivative of zirconium and its preparation

Chemistry of inorganic compounds – Halogen or compound thereof

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423608, C01B 700, C01G 2502

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active

052523101

ABSTRACT:
Reactive derivatives of zirconium, are provided which are in the form of a pulverulent white, non-crystallized solid which is dry in appearance, and consist of metazironic acid, ZrO (OH).sub.2, accompanied by free or weakly bound water, some of the OH.sup.- ions being optionally replaced by halide ions. The ZrO.sub.2 content of these derivatives is from 60 to 92% by weight inclusive, the water content ranges from 3 to 40%, and the halide ion content can range up to approximately 5% by weight. The solid derivatives of the invention can be easily converted into usual reactive derivatives of zirconium by reaction with an aqueous solution of an acid.

REFERENCES:
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patent: 3254949 (1966-06-01), Clearfield
patent: 3334962 (1967-08-01), Clearfield
patent: 4719091 (1988-01-01), Wusirika
patent: 4746497 (1988-05-01), Jenkins et al.
patent: 4786486 (1988-11-01), Giuelen et al.
Inorganic Colloid Chemistry by H. B. Weiser, vol. II (1935) pp. 265-266.
Cotton, et al., Advanced Inorganic Chemistry, 1966, Interscience Pub., pp. 915-916.
Chemical Abstracts, vol. 97, No. 24 (1982), 97:207105m.

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