Phthalocyanine compounds containing either a polymerizable vinyl

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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540135, C09B 4704

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active

055169007

ABSTRACT:
A novel phthalocyanine compound having improved solubility and high purity and containing a polymerizable vinyl group within its molecule is provided. Intermediates to this phthalocyanine compound also have improved solubility and high purity. Further, with the novel phthalocyanine compound used as a starting monomer, a novel polymer is obtained which has a high content of (metal) phthalocyanine and is easy to control the orientation of phthalocyanine rings. The polymer having improved solubility and high purity is expected of use as functional material such as catalysts and recording material.

REFERENCES:
patent: 3482972 (1969-12-01), Idelson
patent: 4663084 (1987-05-01), Shirai et al.
The Journal of Inorganic and Organometallic Polymers, vol. 1, No. 1, Mar. 1991, D. Wohrle, et al., "Low Molecular Weight, Polymeric, and Covalently Bound Cobalt(II)-Phthalocyanines For The Oxidation Of Mercaptans", pp. 115-130.
Macromolecules, 1987, vol. 20, pp. 2665-2669, Mikiharu Kamachi, et al., "Synthesis of New Polymers Containing Porphyrins n Their Side Chains: Radical Polymerizations of 5-[4-(acryloyloxy)phenyl]-10,15,20-triphenylporphyrin and 5-[4-(methacryloyloxy)phenyl]-10,15,20-triphenylporphyrin".
The Journal of Physical Chemistry, vol. 95, No. 1, 1991, H. Shirai, et al., "Functional Metallomacrocycles and Their Polymers. 25. Kinetics and Mechanism of the Biomimetic Oxidation of Thiol by Oxygen Catalyzed by Homogeneous (Polycarboxyphthalocyaninato)Metals", pp. 417-423.
Polymer Preprints, Japan, vol. 42, No. 7, 1993, Mutsumi Kimura, et al., "Synthesis of Novel Water-Soluble Polymers Containing Metallophtalcyanine and Its Catalytic Activity", pp. 2397-2400.

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