Process for the preparation of ketones

Details Process for the preparation of ketones Process for the preparation of ketones

1990-11-19

1992-02-25

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568365, 568309, C07C 4542

Patent

active

050915878

ABSTRACT:
A process for the preparation of ketones which comprises reacting a conjugated diolefin and water in the liquid phase in the presence of a catalyst system comprising:

REFERENCES:
patent: 3836553 (1974-07-01), Fenton
patent: 4117016 (1978-09-01), Hughes
patent: 4414417 (1983-11-01), Mestroni et al.
patent: 4645863 (1987-02-01), Rebafka et al.
Imai et al., "Transfer Hydrogenation and Transfer Hydrogenolysis VII. The Mechanism of Hydrogen Transfer from 2-Propanol to Olefins Catalyzed by Dihydridotetrakis-(Triphenylphosphine)Ruthenium(II)," Bulletin of the Chem. Soc. of Japan, vol. 48 (5), 1585-1589, 1975.
Ying-Rui et al., "Iridium Complex Catalyzed Hydrogen Transfer Reaction of Unsaturated Secondary Alcohols," Acta Chemica Sinica, 46 (1), 1988, pp. 93-95. (Article in Japanese).
Fragale et al., "Dehydrogenation of Sec-Alcohols to Ketones Promoted by Rhodium and Iridium Catalysts and Alkali," Journal of Molecular Catalysis, 5, 1978, pp. 65-73.

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