Silylation of organic compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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556442, 556426, 556470, 556478, 556436, 556415, 556422, 556445, 546 14, 548110, 260404, 260413, 260398, C07F 708, C07F 710, C07F 718

Patent

active

043606865

ABSTRACT:
Active hydrogen-containing compounds are silylated by contacting with trimethylsilyl trichloroacetate at elevated temperatures in the presence of an initiator.

REFERENCES:
Pierce, "Silylation of Organic Compounds", Pierce Chemical Co., Rockford, Ill., 1968, pp. 7-26, 437-445, and 481-482.
E. Nakamura et al., J. Am. Chem. Soc., 98, 2346 (1976).
T. Okada, et al. J. Organometallic Chem., 42, 117, (1972).
H. H. Hergott, et al., Synthesis, 626 (1980).

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