Process for producing carbo-chain homo-polymers, block- and rand

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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260 336UA, 525217, 525250, 525271, 525314, 526340, 526335, 526284, 526346, 5263402, 526337, 525534, 525502, 525 92, 525152, 525132, C08F 448

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042712823

ABSTRACT:
A process for producing carbo-chain homopolymers, block- and random copolymers of conjugated dienes and vinylaromatic monomers comprising polymerization of dienes, vinyl- or di-vinylaromatic monomers or copolymerization thereof in a medium of a hydrocarbon solvent at a temperature ranging from -30.degree. to +150.degree. C. in the presence of an organolithium catalyst of the formula R(Li).sub.x, wherein R is a hydrocarbon radical or a diene polymer, x is an integer of from 1 to 4, and a modifying additive which is a compound comprising a product of interaction between a phenolamine resin and an alkali metal and having the general formula: ##STR1## wherein n is an integer of from 1 to 10;

REFERENCES:
patent: 3294768 (1966-12-01), Wofford
patent: 3496154 (1970-02-01), Wofford
patent: 3718637 (1973-02-01), Hal asa
patent: 3759919 (1973-09-01), Dillenschneider
patent: 3954700 (1976-05-01), Farham

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