Process for synthesis of methoxy substituted methylsilanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 718

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050845896

ABSTRACT:
The present invention is a process for the production of selected methoxysilanes in high yield. The process involves reacting methanol with a silazane at a temperature greater than the boiling point of product methoxysilane and less than the temperature of methanol. Under these temperature conditions rapid removal of product methoxysilanes from the reaction mixture occurs minimizing undesirable reactions which can reduce yield of the process. The described process has been found useful for the production of dimethylmethoxysilane, dimethyldimethoxysilane, and methyldimethoxysilane.

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Viswanathan et al., J. Chem. Soc. 3:487 (1968); The Synthesis and Some Properties of Methoxydimethylsilane.
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Nazran et al.; J. Am. Chem. Soc. 106:7267 (1984); Dimethylsilylene: Its Optical Absorption Spectrum and Reaction Kinetics.

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