Process for haloalkylation of high performance polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

528125, 528126, 528127, 528128, 528171, 528172, 528174, 528373, 528401, 528405, 525471, 525534, 525535, 525540, 524 81, 524167, 524284, 524745, 522 5, 522 71, 522162, 522167, 430311, C08F28300, C08G 1400

Patent

active

057537836

ABSTRACT:
Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units, with an acetyl halide and dimethoxymethane in the presence of a halogen-containing Lewis acid catalyst and methanol, thereby forming a haloalkylated polymer. In a specific embodiment, the haloalkylated polymer is then reacted further to replace at least some of the haloalkyl groups with photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer.

REFERENCES:
patent: 2125968 (1938-08-01), Theimer
patent: 3367914 (1968-02-01), Herbert
patent: 3455868 (1969-07-01), D'Alessandro
patent: 3914194 (1975-10-01), Smith
patent: 4110279 (1978-08-01), Nelson et al.
patent: 4435496 (1984-03-01), Walls et al.
patent: 4623558 (1986-11-01), Lin
patent: 4667010 (1987-05-01), Eldin
patent: 5268444 (1993-12-01), Jensen et al.
patent: 5336720 (1994-08-01), Richards
patent: 5438082 (1995-08-01), Helmer-Metzmann et al.
patent: 5561202 (1996-10-01), Helmer-Metzmann et al.
"Chloromethylation of Condensation Polymers Containing an Oxy-1, 4-Phyenylene Backbone", Polymer Preprints (1979) vol. 20(1), 835, W.Daly, S. Chotiwana, and R. Nielsen.
"Chloromethylstyrene: Synthesis, Polymerization, Transformations, Applications", JMS-Rev. Macromol. Chem. Phys., C22(3), 343-407(1982-83), M.Camps, M.Chatzopoulos, and J-P. Montheard.
"Pulse Radiolysis Studies on the Mechanism of the High Sensitivity of Chloromethylated Polystyrene as an Electron Negative Resist", Lithography, 25(1) (1984), 287, Y. Tabata, S. Tagawa, and M. Washio.
"Deep UV Photochemistry of Copolymers of Trimethyl-Silylmethyl Methacrylate and Chloromethylstrene", Polymer Preprints, 29(1) 546 (1988), M.Jurek, A. Novembre, I. Heyward, R.Gooden, E. Reichmanis.
"Poly(arylene ethers)", Polymer, vol. 29, 358, (Feb., 1988), P. Gergenrother, B. Jensen, and S. Havens.
"Ethynyl-Terminated Polyarylates: Synthesis and Characterization", Journal of Polymer Science: Polymer Chemistry Ed., vol. 22, 3011-3025, (1984), S. Havens.
"Flare, A Low Dielectric Constant, High T.sub.g Thermally Stable Poly(Arylene Esther) . . . ", Polymer Preprints, 37(1), 150, (1996), N.Hendricks and K. Lau.
"Styrene Terminated Resins as Interlevel Dielectrics for Multichip Modules", Polymer Preprints, 32(2), 178, (1991), J.Zupancic, D.Blazej, T.Baker, and E.Dinkel.
"Functional Polymers and Sequential Copolymers by Phase Transfer Catalysis, 2.sup.a) ", Makromol Chem. 185, 1867-1880 (1984), V. Percec and B. Auman.
"Functional Polymers and Sequential Copolymers by Phase Transfer Catalysis, 3.sup.a) ", Makromol Chem. 185, 23199-2336, (1984), V. Percec and B. Auman.
"Functional Polymers and Sequential Copolymers by Phase Transfer Catalysis", Polymer Bulletin 10, 223-230 (1983), V. Percec and P. Rinaldi. Ether", Synthesis, 970 (1979), J. Amato, S. Karady, M. Sletzinger, and L. Weinstock.
"A Simple and Inexpensive Procedure for Chloromethylation of Certain Aromatic Compounds", Tetrahedron Letters, vol. 24(18), 1993-1936, (1983), A. McKillop, F.A. Madjdabadi, and D. Long.
"Synthesis of Intermediates for Production of Heat Resistant Polymers (Chloromethylation of Diphenyl Oxide)", Zhurnai Prikladnoi Khimii, vol. 40 (11), 2540-2546, (Nov., 1967), E., Tepenitsyna, M. Farberov, and A. Ivanovskii.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for haloalkylation of high performance polymers does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for haloalkylation of high performance polymers, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for haloalkylation of high performance polymers will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1854249

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.