Polymerization of cyclic poly(aryl ether) oligomers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528 86, 528126, 528128, 528170, 528172, 528174, 528190, 528211, 528216, 528220, 528226, 528228, C08G 802, C08G 1400

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active

052645207

ABSTRACT:
This invention is a process for the preparation of poly(aryl ethers) from cyclic poly(aryl ether) oligomers. These low melt viscosity cyclic oligomers undergo ring opening and chain extension upon heating in the presence of a catalyst, forming high molecular weight linear polymers with no coproduct formation. Finished thermoplastic parts and composites may be prepared using this technology with processing techniques normally restricted to thermosetting monomers.

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patent: 5110893 (1992-05-01), Fukuyama
Cella, et al., Ring Opening Polymerization of Cyclic Ethers & Thioethers, Imides, Sulfones via Aromatic Ether-Ether Exchange; Amer. Chem. Soc. Polymer Prep. vol. 30, No. 2 (1989), pp. 142-143.
Cella, et al., Poly. Prepr. 30(2), 581.varies.582, (Sep. 1989).

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