Two component waterborne urethane/vinyl polymer composite for co

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524591, 525123, 525455, C08J 300, C08K 320, C08L 7500, C08F 830, C08F28304

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active

060666927

ABSTRACT:
A heterogeneous two component waterborne urethane/vinyl polymer composition, the method of making the composition, and the coating derived therefrom. The composition is a low or zero VOC composition containing a polyol stabilized non-functional, high Tg, aqueous vinyl polymer latex, a water dispersible polyisocyanate, and, optionally, a polyhydric alcohol. The composition is formed by emulsion polymerizing one or more vinyl monomers which will form a high Tg polymer, in the presence of an emulsifier containing one or more acid-containing polyols which have been neutralized with one or more reactive amines, and combining the resulting polyol-stabilized high Tg aqueous vinyl polymer latex with a water-dispersible polyisocyanate and, optionally, a polyhydric alcohol.

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S. T. Eckersley, et al., "Mechanistic Considerations of Particle Size Effects on Film Properties of Hard/Soft Latex Blends," Journal of Coatings Technology, vol. 69, No. 864, Jan. 1997, pp. 97-107.

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