Indolins styryl-like compounds

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2602433, 2602444, 2602455, 2602456, 2602457, 542415, 542401, 542432, 542434, 544 32, 544 89, 544242, 544333, 546270, 548121, 548159, 548150, 548217, C07D49804

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043140580

ABSTRACT:
This invention relates to color-changing stryl-like compounds and the preparing of the same. A compound according to the present invention has, as its principal ring, an indoline ring of 2nd position, and has, at stimulation reversible or irreversible change(s) between a closed ring structre of a non-plane molecular structure indicated by the following chemical formula(1) showing white or pale color, and an open ring structure of a plane molecular structure indicated by the following chemical formula(2) showing vivid visible color: ##STR1## Wherein Q represents benzene ring with or without substituted radicals and/or condensed ring(s); R.sub.1 and R.sub.2 represent lower alkyl radicals hydroxyalkyl radicals or alkoxyalkyl radicals of the same or different kinds,; R.sub.3 represents hydrogen, alkyl radical, alkoxy radical, halogen, nitrile radical, aromatic radical or phenoxy radical; Y represents oxygen (O) or sulfer (S); Z represents alkylene radical of carbon number of 2 to 4 with or without alkyl substitution radical(s) necessary to form a ring structure together with ##STR2## A represents a condensation reaction residue of an aromatic aldehyde, heterocyclic aldehyde, aromatic nitroso compound, or heterocyclic nitroso compound. And X represents an anion.

REFERENCES:
patent: 3860583 (1975-01-01), Schmitt
patent: 3904613 (1975-09-01), Schmitt
patent: 3975379 (1976-08-01), Schmitt
Chemischerr Informationsdienst 1974, #5-262.

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