Metalation of polymers

Details Metalation of polymers Metalation of polymers

1975-07-29

1976-08-31

Schofer, Joseph L.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

526 20, 526 47, 526 2W, C08L 5100, C08L 5300, C08F 600, C08F 800

Patent

active

039781615

ABSTRACT:
Hydrocarbon polymers are readily metalated in solution in a hydrocarbon solvent with metallic sodium, potassium, rubidium and/or cesium utilizing a chelating polytertiary amine or a crown polyether.

REFERENCES:
patent: 3492369 (1970-01-01), Naylor
patent: 3627837 (1971-12-01), Webb
patent: 3703566 (1972-11-01), Duck et al.
Morton, "Metalation of Polystyrene," Journal of Organic Chemistry, 24, pp. 1167-1169, (1959).

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