Process for the production of esters

Details Process for the production of esters Process for the production of esters

1986-08-25

1987-05-12

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560204, 560232, 560233, 560234, 560114, 260410, 562406, 562497, 562522, C07C 6976

Patent

active

046652132

ABSTRACT:
Carboxylic acid esters are produced by reacting an olefinic hydrocarbon with an ester of formic acid in the presence of both carbon monoxide and oxygen at a temperature of up to 200.degree. and a pressure of up to 300 bar in the presence of water, typically in an amount of from 0.01 to 5% w/w, a source of protons, which is preferably a mineral acid or a tectometallosilicate in the hydrogen form, and as catalyst (a) a source of palladium, and (b) a source of copper.

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Bryant, F. J. et al, ACS Dir. Pet. Chem. 18,(1) Feb. 1977, pp. 193-195.

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