Method for preparing siloxane-carbonate block copolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525474, 528 25, 528 29, C08G 7742, C08G 6362

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046579893

ABSTRACT:
Siloxane-carbonate block copolymers are prepared by reacting (A) at least one siloxane compound with (B) at least one polycarbonate compound, one of reagents A and B being anionic and the other being reactive with nucleophiles. The siloxane compound is preferably a linear chlorosilane-terminated polysiloxane, a cyclic polysiloxane or a "living" polysiloxane anion. The polycarbonate composition may be a cyclic polycarbonate oligomer composition, preferably an oligomer mixture, or may be prepared by the reaction of such an oligomer composition with a polycarbonate formation catalyst such as tetramethylammonium tetraphenylborate.

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patent: 3819744 (1974-06-01), Buchner et al.
patent: 4080400 (1978-03-01), Martin
patent: 4102940 (1978-07-01), Thom et al.
"Microdomains in Alternating Block Polymers of Dimethylsiloxane and Bisphenol-A Carbonate", Polymer Letters, vol. 7, pp. 573-577 (1969).

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