Synthesis of (alkoxyalkyl) amines

Details Synthesis of (alkoxyalkyl) amines Synthesis of (alkoxyalkyl) amines

1984-04-26

1986-05-13

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

564503, C07C 9304

Patent

active

045888434

ABSTRACT:
It has been discovered that when reaction is effected between an alkali metal omega-amino-alkoxide and an alkyl halide, nucleophilic attack of the alkoxide on the alkyl halide occurs so that an (alkoxyalkyl)amine is formed. The conventional Hofmann displacement reaction (elimination of CH.sub.3 Br) does not occur to any significant extent. Nor does the common olefin elimination reaction occur to any significant extent when using alkali metal omega-aminoalkoxides having one or two C.sub.2 or higher alkyl substituents on the nitrogen atom.

REFERENCES:
patent: 3480675 (1969-11-01), Poppelsdorf
Fakstrop et al., "Bifunctional Amines and Ammonium Compounds" Acta Chemica Scand. 7 (1953), pp. 134-139.
Surrey, "Name Reactions in Organic Chemistry" Academic Press Inc. NY (1954), pp. 169-170.

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