Phosphine and phosphonium compounds and catalysts

Details Phosphine and phosphonium compounds and catalysts Phosphine and phosphonium compounds and catalysts

1982-09-27

1984-09-25

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260429R, 2604295, 260439R, 260440, 260441, 260430, 2604381, C07F 1702, C07F 1500, C07F 1502

Patent

active

044735057

ABSTRACT:
Novel ligand materials and transition metal complexes thereof are disclosed which are useful as solvents and/or catalysts for various processes, including catalytic conversion processes for the conversion of hydrocarbons or carbon monoxide, such as the hydrocarbonylation of olefins, hydrogenation using H.sub.2 or CO and H.sub.2 O, dehydrogenation, hydrocarbon synthesis, alcohol synthesis, and water-gas disproportionation catalysis. Among the novel ligand materials disclosed are compositions containing phosphine and arsine coordinating groups along with, e.g., groups comprising fluorines, ethynyl or ethenyl groups, quaternary ammonium, arsonium and/or phosphonium groups. Ligands containing M--O--L linkages and complexes thereof are also disclosed wherein M is selected from, for example, Si or Ti and L is selected from P or As. Also, various ion-exchanged ligand compositions, photoreactive compositions and the uses of such compositions are also described.

REFERENCES:
patent: 3657298 (1972-04-01), King et al.
patent: 4008281 (1977-02-01), Knowles et al.
patent: 4138420 (1979-02-01), Unruh et al.
patent: 4152344 (1979-05-01), Unruh
patent: 4201714 (1980-05-01), Hughes
patent: 4209554 (1980-06-01), Traynor et al.
Kosolapoff et al., Organic Phosphorus Compounds, Wiley-Interscience, N.Y., vol. 1, pp. 461, 475, 482, 484 (1972).
Chemical Communications, pp. 1559-1561 (1968), A. J. Carty et al.
Journal of Organometallic Chemistry, 50 (1973), 247-263, by H. A. Patel, A. J. Carty and N. K. Hota.
Chemical Abstracts vol. 80, 1974, p. 356, Zh. Obshch. Khim. 1974, 44(1), 103-106 (Russ).
Tetrahedron, vol. 27, pp. 3893 to 3907, 1971, "Interactions In Acetylenes".

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