Separation of methyl T-butyl ether from close boiling C.sub.5 hy

Distillation: processes – separatory – Adding material to distilland except water or steam per se – Organic compound

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203 58, 203 60, 203 62, 203 63, 203 64, 568699, 585856, 585857, 585860, 585864, 585865, 585866, B01D 340, C07C 708, C07C 4142

Patent

active

052289575

ABSTRACT:
The separation by conventional distillation or rectification of methyl t-butyl ether from close boiling hydrocarbons is difficult because of the closeness of their vapor pressures. Methyl t-butyl ether can be readily separated from these by extractive distillation. Examples of effective agents are: from 1-pentene, dimethylsulfoxide; from cyclopentane, sulfolane and from n-pentane - cyclopentane mixtures, diethyl malonate.

REFERENCES:
patent: 4148695 (1979-04-01), Lee et al.
patent: 4513153 (1985-04-01), Sandrin
patent: 4661209 (1987-04-01), Berg
patent: 5160414 (1992-11-01), Lee et al.

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