Bimetallic complexes as catalysts in an oxidation process

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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556 1, 556 28, 556 45, 556137, 556150, C07D30106, C07D30304, C07D30306

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active

052236315

ABSTRACT:
Disclosed is an olefin epoxidation process that contacting an olefinically unsaturated substrate with oxygen in the presence of catalytic amount of a bimetallic complex under the reaction conditions such that the olefin is at least partially oxidized. The metals introduced in the bimetallic complex are independently selected from vanadium, chromium, manganese, iron, cobalt, nickel, copper, molybdenum, ruthenium, rhodium, palladium, tungsten, rhenium, osmium, iridum or platinum.

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patent: 3843691 (1974-10-01), Bouboulis
patent: 3935272 (1976-01-01), Chapurdit
patent: 4256649 (1981-03-01), Dyer
patent: 4822899 (1989-04-01), Groves et al.

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