Process for the preparation of random copolymers of mono-olefins

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 336UA, 260 4229, 260 8072, 428461, 428462, C08F21000, C08F 406, C08F 442

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active

039391299

ABSTRACT:
A process is described for the preparation of substantially linear, amorphous random copolymers of mono-olefins or mono-olefins and unconjugated dienes with N-unsaturated lactams.
At least two mono-olefins containing 2 to 20 carbon atoms, and possibly an unconjugated diene, are placed in contact, in an inert liquid medium at a temperature of between -80.degree. and +150.degree.C, with at least one such N-unsaturated lactam in the form of a complex with a Lewis acid, in the presence of a co-ordination catalyst system, until a copolymer forms.
The resulting copolymers can be vulcanized, and among other properties have improved adherence to metal surfaces.

REFERENCES:
patent: 3821172 (1974-06-01), Sugiura et al.

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