Process for the production of methyl tert.-butyl ether (MTBE) an

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568699, C07C 4106

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active

045032653

ABSTRACT:
In the reaction of methanol and of i-butene which is contained in a hydrocarbon mixture on an acid cation exchange material to give methyl tert.-butyl ether (MTBE), methanol and i-butene can be used in essentially equimolar amounts if simultaneously to the distillative separation of the etherification mixture into its constituents this etherification mixture is passed into a secondary reaction. To do this, the etherification mixture is fed into a distillation column and from above the feed-in point a liquid distillate stream is taken off and passed in a secondary reactor over an acid cation exchange material. The mixture leaving the secondary reactor is returned below its take-off point.

REFERENCES:
patent: 3979461 (1976-09-01), Ancillotti et al.
patent: 4320232 (1982-03-01), Volkamer et al.

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