Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1980-02-04
1983-09-13
Smith, Edward J.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
252429B, 526124, 526351, 526905, 526906, C08F 464, C08F 1004
Patent
active
044043414
ABSTRACT:
In a process for producing an olefin polymer or copolymer by polymerizing an alpha-olefin having at least 3 carbon atoms or copolymerizing such alpha-olefins with each other or such an alpha-olefin with up to 20 mole % of ethylene and/or a diene in the presence of a catalyst comprising (1) a solid titanium catalyst component having magnesium, halogen, titanium, phosphorus and a carboxylic acid ester and (2) an organometallic compound of a metal of Groups I to III of the Mendelejeff's periodic table; the improvement wherein said catalyst is composed of (A) the solid titanium catalyst component (1) in which the molar ratio of the phosphorus to the carboxylic acid ester is from about 0.05 to about 2 and which has a specific surface area of not less than about 40 m.sup.2 /g, (B) the organometallic compound (2), and (C) an electron donor; and a catalyst used for aforesaid process.
REFERENCES:
patent: 4069169 (1978-01-01), Toyoda et al.
patent: 4130503 (1978-12-01), Fodor
patent: 4180636 (1979-12-01), Hirota et al.
patent: 4187196 (1980-02-01), Giannini et al.
patent: 4229558 (1980-10-01), Kakogawa et al.
Kashiwa Norio
Toyota Akinori
Ushida Yoshihisa
Mitsui Petrochemical Industries Ltd.
Smith Edward J.
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