Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Patent
1993-03-15
1994-02-22
Dentz, Bernard
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
502209, C07D30760
Patent
active
052888800
ABSTRACT:
The present invention provides a process for the manufacture of maleic anhydride by the vapor phase catalytic oxidation of n-butane with molecular oxygen by the use of a specially prepared phosphorus vanadium-oxygen composite catalyst containing specific kind of a divalent metal. The catalyst used in the present invention is prepared from a mixture of vanadyl hydrogen orthophosphate and at least one compound selected from the group consisting of a divalent metal hydrogen orthophosphate (Divalent metal is selected from Mg, Ca, Ba, Mn, Fe, Co, Ni, Cu, and Zn.), a divalent metal ammonium orthophosphate (Divalent metal is the same as above.), and a divalent metal orthophosphate (Divalent metal is the same as above.), with the atomic ratio of the divalent metal/vanadium of 0.003-0.5, by calcining the mixture at 300.degree.-400.degree. C., and then pretreating said catalyst in an inert gas or a mixed gas containing n butane and molecular oxygen at 350.degree.-700.degree. C. Maleic anhydride can be manufactured at a high conversion, a high selectivity and a high yield according to the present invention.
REFERENCES:
patent: 3862146 (1975-01-01), Boghosian
patent: 3987063 (1976-10-01), Lemal et al.
Shokubai, vol. 33, No. 2 pp. 115-118 (1991).
Dentz Bernard
Maruzen Petrochemical Co. Ltd.
Stoltz Melvin I.
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