Compositions: coating or plastic – Coating or plastic compositions – Metal-depositing composition or substrate-sensitizing...
Patent
1992-07-20
1994-04-26
Klemanski, Helene
Compositions: coating or plastic
Coating or plastic compositions
Metal-depositing composition or substrate-sensitizing...
C23C 1836
Patent
active
053063341
ABSTRACT:
Phosphorus-containing, crystalline, nickel-coated fabric, wherein said nickel contains 1 to 6 weight percent phosphorus, has crystallites greater than 3 nanometers and has a surface resistivity of less than 1 ohm/square is deposited onto a substrate a surface which is catalytic to electroless deposition of nickel by immersing the substrate into an electroless nickel plating solution consisting essentially of nickel salt, one or more organic acids, hypophosphite reducing agent, thiourea and ammonia and essentially no heavy metal, wherein the concentration of said thiourea is less than 1 ppm, maintained at a pH of 6.5 to 8.5 and a temperature less than 60.degree. C. Preferred plating solutions comprise essentially no lead or cadmium and have a molar ratio of nickel to hypophosphite in said solution is 0.4 to 0.55. Preferred organic acids are selected from the group consisting of lactic acid, acetic acid, propionic acid, pyruvic acid, aspartic acid and glycolic acid.
REFERENCES:
patent: 3686020 (1972-08-01), Coll-Palagos
patent: 3971861 (1976-07-01), de Waltoff
patent: 3977884 (1976-08-01), Gulla et al.
Electroless Nickel Plating, Wolfgang Riedel; ASM International, Metals Park, Ohio, USA; Finishing Pub., Ltd., Stevenage Hertfordshire, England, pp. title pp. 13, 17-25, 41-44, 50-51, 64-70, 101-104, 245-251, 1991.
Martyak Nicholas M.
Monzyk Bruce F.
Kelley Thomas E.
Klemanski Helene
Monsanto Company
Wachter Mark F.
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