Process for making polyetheresters with high aromatic ester cont

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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522 1, 522 93, 522102, 524777, 524783, 524784, 524785, 524786, 524845, 525437, 528176, 528193, 528194, 528272, 528275, 528280, 528281, 528282, 528283, 528286, 528306, 528307, C08G 6378

Patent

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056124449

ABSTRACT:
A two-step process for making polyetherester resins is disclosed. A low molecular weight polyol reacts with an aromatic dicarboxylic acid in step one to produce a polyester intermediate. In step two, the polyester intermediate reacts with an anhydride or an aliphatic dicarboxylic acid in the presence of an insertion catalyst to produce a polyetherester resin that contains greater than about 10 wt. % of recurring units derived from the aromatic dicarboxylic acid. The polyetheresters are useful for making thermoset resins with excellent mechanical properties and chemical resistance.

REFERENCES:
patent: 4605729 (1986-08-01), Barnes et al.
patent: 5436314 (1995-07-01), Yang et al.

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