High performance carbon filament structures

Chemistry of inorganic compounds – Carbon or compound thereof – Elemental carbon

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4234473, 4234475, D01F 912

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054138663

ABSTRACT:
High performance carbon filaments are provided which are characterized as having; (i) a surface area from about 50 m.sup.2 /g to 800 m.sup.2 /g, (ii) an electrical resistivity from about 0.3 .mu.ohm.m to 0.8 .mu.ohm.m, (iii) a crystallinity from about 5% to about 100%, (iv) a length from about 1 .mu.m to about 100 .mu.m, and (v) a shape which is selected from the group consisting of branched, spiral, and helical. Also provided is a carbon fiber structure suitable for use in high performance composites which structure is characterized by a primary carbon fiber structure having carbon filaments grown therefrom. The carbon filaments are grown from the carbon fibers by use of an alloy catalyst comprised of a first metal selected from Group IB of the Periodic Table of the Elements, and one or more metals from a second group of metals selected from iron, nickel, cobalt, and zinc; and optionally a metal from a third group of metals selected from titanium, tungsten, tin, and tantalum.

REFERENCES:
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J. L. Figueiredo et al.; Carbon Fibers Filaments and Composites, NATO ASI Series E; Applied Sciences, pp. 73-94, vol. 177, 1989.
Bernardo et al.; Carbon Deposition and Methane Steam Reforming on Silica-Supported Ni-Cu Catalysts; Journal of Catalysis; 96, 517-534 (1985).
Nishiyama et al.; Carbon Formation on Copper-Nickel Alloys from Benzene; Journal of Catalysis, 33, 98-107 (1974).
Nishiyama et al.; Effect of Hydrogen on Carbon Deposition Catalyzed by Copper-Nickel Alloys; Journal of Catalysis, 45, 1-5 (1976).
Tavares et al.; Reactivity of Carbon Deposited on Nickel-Copper Alloy Catalysts from the Decomp of Methane; Journal of Catalysis, 100, 545-548 (1986).
R. T. K. Baker; Catalytic Growth of Carbon Filaments; Carbon vol. 27, No. 3 pp. 315-323; 1989.

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